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| ?? | |||
|---|---|---|---|
| IUPAC ??
Nitromethane
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| ??? (PIN)
Nitromethane[1] | |||
| ??
Nitrocarbol
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| ??? | |||
3D ?? (JSmol)
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| ChEBI | |||
| ChEMBL | |||
| ChemSpider | |||
| ECHA InfoCard | 100.000.797 | ||
| KEGG | |||
PubChem CID
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| RTECS ?? |
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| UNII | |||
CompTox Dashboard (EPA)
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| ?? | |||
| CH3NO2 | |||
| ? ?? | 61.04 g/mol | ||
| ??? | colorless, oily liquid[2] | ||
| ?? | Light, fruity[2] | ||
| ?? | 1.1371 g/cm3 (20 °C)[3] | ||
| ??? | ?28.7 °C (?19.7 °F; 244.5 K)[3] | ||
| ??? | 101.2 °C (214.2 °F; 374.3 K)[3] | ||
| ??? (T, P) | 588 K, 6.0 MPa[4] | ||
| ca. 10 g/100 mL | |||
| ??? | miscible in ???? ??, ???, ???[3] | ||
| ?? ?? | 28 mmHg (20 °C)[2] | ||
| ??? (pKa) | 17.2 in DMSO; 10.21 in water[5][6] | ||
??? (χ)
|
-21.0·10?6 cm3/mol[7] | ||
| ???? | 0.204 W/(m·K) at 25 °C[8] | ||
??? (nD)
|
1.3817 (20 °C)[3] | ||
| ?? | 0.63 cP at 25 °C[8] | ||
| 3.46[9] | |||
| ???[10] | |||
??? (C)
|
106.6 J/(mol·K) | ||
?? ? ???? (S
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171.8 J/(mol·K) | ||
?? ?? ??? (ΔfH?298)
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-112.6 kJ/mol | ||
??? ?? ??? (ΔfG?)
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-14.4 kJ/mol | ||
| ?? | |||
| ?? ?? | Flammable, health hazard | ||
| GHS ???? |    
| ||
| ??? | ?? | ||
| H203, H226, H301, H331, H351 | |||
| P210, P261, P280, P304+340, P312, P370+378, P403+233 | |||
| NFPA 704 (??? ?????) | |||
| ??? | 35[9] °C (95 °F; 308 K) | ||
| 418[9] °C (784 °F; 691 K) | |||
| ?? ?? | 7–22%[9] | ||
?????? ???? (TLV)
|
20 ppm[9] | ||
| ?? ??? ?? ?? ???? (LD, LC): | |||
LD50 (median dose)
|
940 mg/kg (oral, rat) 950 mg/kg (oral, mouse)[11] | ||
LDLo (lowest published)
|
750 mg/kg (rabbit, oral) 125 mg/kg (dog, oral)[11] | ||
LCLo (lowest published)
|
7087 ppm (mouse, 2 h) 1000 ppm (monkey) 2500 ppm (rabbit, 12 h) 5000 ppm (rabbit, 6 h)[11] | ||
| NIOSH (?? ?? ?? ??): | |||
PEL (??)
|
TWA 100 ppm (250 mg/m3)[2] | ||
REL (??)
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none[2] | ||
IDLH (??? ??)
|
750 ppm[2] | ||
| ?? ??? | |||
| nitroethane | |||
?? ???
|
methyl nitrite methyl nitrate | ||
?? ??? ??? ????, ????(25 °C [77 °F], 100 kPa)?? ??? ??? ???.
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???????(nitromethane)? ???? ?????? ?? ???? ?????. ???? ?? ?? ??? ???.
??
[??]- ↑ 〈Front Matter〉. 《Nomenclature of Organic Chemistry : IUPAC Recommendations and Preferred Names 2013 (Blue Book)》. Cambridge: The Royal Society of Chemistry. 2014. 662?. doi:10.1039/9781849733069-FP001. ISBN 978-0-85404-182-4.
- ↑ ? ? ? ? ? ? NIOSH Pocket Guide to Chemical Hazards. “#0457”. ?? ?? ????????? (NIOSH).
- ↑ ? ? ? ? ? Haynes, p. 3.414
- ↑ Haynes, p. 6.69
- ↑ Haynes, p. 5.94
- ↑ Reich, Hans. “Bordwell pKa table: "Nitroalkanes"”. 《University of Wisconsin Chemistry Department》. 2016? 1? 17?? ???.
- ↑ Haynes, p. 3.576
- ↑ ? ? Haynes, p. 6.231
- ↑ ? ? ? ? ? Haynes, p. 15.19
- ↑ Haynes, p. 5.20
- ↑ ? ? ? “Nitromethane”. 《Immediately Dangerous to Life and Health Concentrations (IDLH)》. National Institute for Occupational Safety and Health (NIOSH).
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